Environmental Information
www.ISC-Bio.org/EEL
Polychlorinated Biphenyls
    
[209 PCB congeners]

Congener descriptors (far right column in table) refer to positions on the PCB molecule that can be
chlorinated.  See the picture of the PCB backbone
(below table) and the locations of ortho, para, and meta
positions that can be chlorinated.  

CP0 / CP1:   These 68 coplanar congeners fall into one of two groups. The first group of 20 congeners consists of
those with chlorine substitution at none of the
ortho positions on the biphenyl backbone and are referred to as CP0 or
non-
ortho congeners. The second group of 48 congeners includes those with chlorine substitution at only one of the
ortho positions and are referred to as CP1 or mono-ortho congeners.

4CL :  These 169 congeners have a total of four or more chlorine substituents, regardless of position.

PP :     These 54 congeners have both para positions chlorinated.

2M :     These 140 congeners have two or more of the meta positions chlorinated.


Twelve congeners display all four characteristics and are "dioxin-like" in their structural features and
toxicity to animals [
"dioxin" is 2,3,7,8-tetrachlorodibenzo-p-dioxin (2378-TCDD)].  The dioxin-like congeners
include PCBs 77, 81, 105, 114, 118, 123, 126, 156, 157, 167, 169 & 189
.



IUPAC Name            BZ Congener Number        CASRN    Descriptors
Biphenyl                                                      0                                         92-52-4         
2-Chlorobiphenyl                                       1                                         2051-60-7         CP1
3-Chlorobiphenyl                                       2                                         2051-61-8         CP0
4-Chlorobiphenyl                                       3                                         2051-62-9         CP0
2,2'-Dichlorobiphenyl                                4                                         13029-08-8         
2,3-Dichlorobiphenyl                                 5                                         16605-91-7         CP1
2,3'-Dichlorobiphenyl                                6                                         25569-80-6         CP1
2,4-Dichlorobiphenyl                                 7                                         33284-50-3         CP1
2,4'-Dichlorobiphenyl                                8                                         34883-43-7         CP1
2,5-Dichlorobiphenyl                                 9                                         34883-39-1         CP1
2,6-Dichlorobiphenyl                                10                                         33146-45-1         
3,3'-Dichlorobiphenyl                               11                                         2050-67-1         CP0, 2M
3,4-Dichlorobiphenyl                                12                                         2974-92-7         CP0
3,4'-Dichlorobiphenyl                               13                                         2974-90-5         CP0
3,5-Dichlorobiphenyl                                14                                         34883-41-5         CP0, 2M
4,4'-Dichlorobiphenyl                               15                                         2050-68-2         CP0, PP
2,2',3-Trichlorobiphenyl                           16                                         38444-78-9         
2,2',4-Trichlorobiphenyl                           17                                        37680-66-3         
2,2',5-Trichlorobiphenyl                           18                                         37680-65-2         
2,2',6-Trichlorobiphenyl                            19                                         38444-73-4         
2,3,3'-Trichlorobiphenyl                            20                                        38444-84-7         CP1, 2M
2,3,4-Trichlorobiphenyl                             21                                         55702-46-0         CP1
2,3,4'-Trichlorobiphenyl                            22                                         38444-85-8         CP1
2,3,5-Trichlorobiphenyl                             23                                         55720-44-0         CP1, 2M
2,3,6-Trichlorobiphenyl                             24                                         55702-45-9         
2,3',4-Trichlorobiphenyl                            25                                         55712-37-3         CP1
2,3',5-Trichlorobiphenyl                            26                                         38444-81-4         CP1, 2M
2,3',6-Trichlorobiphenyl                            27                                         38444-76-7         
2,4,4'-Trichlorobiphenyl                            28                                         7012-37-5         CP1, PP
2,4,5-Trichlorobiphenyl                            29                                         15862-07-4         CP1
2,4,6-Trichlorobiphenyl                            30                                         35693-92-6         
2,4',5-Trichlorobiphenyl                            31                                        16606-02-3         CP1
2,4',6-Trichlorobiphenyl                            32                                         38444-77-8                 
2,3',4'-Trichlorobiphenyl                           33                                         38444-86-9         CP1
2,3',5'-Trichlorobiphenyl                           34                                         37680-68-5         CP1, 2M
3,3',4-Trichlorobiphenyl                            35                                         37680-69-6         CP0, 2M
3,3',5-Trichlorobiphenyl                            36                                         38444-87-0         CP0, 2M
3,4,4'-Trichlorobiphenyl                            37                                         38444-90-5         CP0, PP
3,4,5-Tricholobiphenyl                              38                                         53555-66-1         CP0, 2M
3,4',5-Trichlorobiphenyl                            39                                         38444-88-1         CP0, 2M
2,2',3,3'-Tetrachlorobiphenyl                    40                                         38444-93-8         4CL, 2M
2,2',3,4-Tetrachlorobiphenyl                     41                                         52663-59-9         4CL
2,2',3,4'-Tetrachlorobiphenyl                    42                                         36559-22-5         4CL
2,2',3,5-Tetrachlorobiphenyl                     43                                         70362-46-8         4CL, 2M
2,2',3,5'-Tetrachlorobiphenyl                     44                                         41464-39-5         4CL, 2M
2,2',3,6-Tetrachlorobiphenyl                      45                                         70362-45-7         4CL
2,2',3,6'-Tetrachlorobiphenyl                     46                                         41464-47-5         4CL
2,2',4,4'-Tetrachlorobiphenyl                     47                                         2437-79-8         4CL, PP
2,2',4,5-Tetrachlorobiphenyl                      48                                         70362-47-9         4CL
2,2',4,5'-Tetrachlorobiphenyl                     49                                         41464-40-8         4CL
2,2',4,6-Tetrachlorobiphenyl                      50                                         62796-65-0         4CL
2,2',4,6'-Tetrachlorobiphenyl                      51                                         68194-04-7         4CL
2,2',5,5'-Tetrachlorobiphenyl                      52                                         35693-99-3         4CL, 2M
2,2',5,6'-Tetrachlorobiphenyl                      53                                         41464-41-9         4CL
2,2',6,6'-Tetrachlorobiphenyl                      54                                         15968-05-5         4CL
2,3,3',4-Tetrachlorobiphenyl                       55                                         74338-24-2         CP1, 4CL, 2M
2,3,3',4'-Tetrachlorobiphenyl                      56                                         41464-43-1         CP1, 4CL, 2M
2,3,3',5-Tetrachlorobiphenyl                       57                                         70424-67-8         CP1, 4CL, 2M
2,3,3',5'-Tetrachlorobiphenyl                      58                                         41464-49-7         CP1, 4CL, 2M
2,3,3',6-Tetrachlorobiphenyl                       59                                         74472-33-6         4CL, 2M
2,3,4,4'-Tetrachlorobiphenyl                       60                                         33025-41-1         CP1, 4CL, PP
2,3,4,5-Tetrachlorobiphenyl                        61                                         33284-53-6         CP1, 4CL, 2M
2,3,4,6-Tetrachlorobiphenyl                        62                                         54230-22-7         4CL
2,3,4',5-Tetrachlorobiphenyl                       63                                        74472-34-7         CP1, 4CL, 2M
2,3,4',6-Tetrachlorobiphenyl                       64                                        52663-58-8         4CL
2,3,5,6-Tetrachlorobiphenyl                        65                                        33284-54-7         4CL, 2M
2,3',4,4'-Tetrachlorobiphenyl                       66                                        32598-10-0         CP1, 4CL, PP
2,3',4,5-Tetrachlorobiphenyl                        67                                         73575-53-8         CP1, 4CL, 2M
2,3',4,5'-Tetrachlorobiphenyl                       68                                        73575-52-7         CP1, 4CL, 2M
2,3',4,6-Tetrachlorobiphenyl                        69                                        60233-24-1         4CL
2,3',4',5-Tetrachlorobiphenyl                        70                                        32598-11-1         CP1, 4CL, 2M
2,3',4',6-Tetrachlorobiphenyl                        71                                        41464-46-4         4CL
2,3',5,5'-Tetrachlorobiphenyl                        72                                        41464-42-0         CP1, 4CL, 2M
2,3',5',6-Tetrachlorobiphenyl                        73                                        74338-23-1         4CL, 2M
2,4,4',5-Tetrachlorobiphenyl                         74                                        32690-93-0         CP1, 4CL, PP
2,4,4',6-Tetrachlorobiphenyl                         75                                        32598-12-2         4CL, PP
2,3',4',5'-Tetrachlorobiphenyl                        76                                       70362-48-0         CP1, 4CL, 2M
3,3',4,4'-Tetrachlorobiphenyl                         77                                       32598-13-3         CP0, 4CL, PP, 2M
3,3',4,5-Tetrachlorobiphenyl                          78                                       70362-49-1         CP0, 4CL, 2M
3,3',4,5'-Tetrachlorobiphenyl                         79                                      41464-48-6         CP0, 4CL, 2M
3,3',5,5'-Tetrachlorobiphenyl                         80                                      33284-52-5         CP0, 4CL, 2M
3,4,4',5-Tetrachlorobiphenyl                          81                                     70362-50-4         CP0, 4CL, PP, 2M
2,2',3,3',4-Pentachlorobiphenyl                     82                                     52663-62-4         4CL, 2M
2,2',3,3',5-Pentachlorobiphenyl                     83                                     60145-20-2         4CL, 2M
2,2',3,3',6-Pentachlorobiphenyl                     84                                      52663-60-2         4CL, 2M
2,2',3,4,4'-Pentachlorobiphenyl                     85                                      65510-45-4         4CL, PP
2,2',3,4,5-Pentachlorobiphenyl                      86                                      55312-69-1         4CL, 2M
2,2',3,4,5'-Pentachlorobiphenyl                     87                                     38380-02-8         4CL, 2M
2,2',3,4,6-Pentachlorobiphenyl                      88                                     55215-17-3         4CL
2,2',3,4,6'-Pentachlorobiphenyl                     89                                     73575-57-2         4CL
2,2',3,4',5-Pentachlorobiphenyl                     90                                     68194-07-0         4CL, 2M
2,2',3,4',6-Pentachlorobiphenyl                     91                                     68194-05-8         4CL
2,2',3,5,5'-Pentachlorobiphenyl                     92                                     52663-61-3         4CL, 2M
2,2',3,5,6-Pentachlorobiphenyl                      93                                    73575-56-1         4CL, 2M
2,2',3,5,6'-Pentachlorobiphenyl                     94                                     73575-55-0         4CL, 2M
2,2',3,5',6-Pentachlorobiphenyl                     95                                     38379-99-6         4CL, 2M
2,2',3,6,6'-Pentachlorobiphenyl                     96                                     73575-54-9         4CL
2,2',3,4',5'-Pentachlorobiphenyl                    97                                     41464-51-1         4CL, 2M
2,2',3,4',6'-Pentachlorobiphenyl                    98                                     60233-25-2         4CL
2,2',4,4',5-Pentachlorobiphenyl                     99                                     38380-01-7         4CL, PP
2,2',4,4',6-Pentachlorobiphenyl                   100                                   39485-83-1         4CL, PP
2,2',4,5,5'-Pentachlorobiphenyl                   101                                 37680-73-2         4CL, 2M
2,2',4,5,6'-Pentachlorobiphenyl                   102                                 68194-06-9         4CL
2,2',4,5',6-Pentachlorobiphenyl                   103                                 60145-21-3         4CL
2,2',4,6,6'-Pentachlorobiphenyl                   104                                 56558-16-8         4CL
2,3,3',4,4'-Pentachlorobiphenyl                   105                                 32598-14-4         CP1, 4CL, PP, 2M
2,3,3',4,5-Pentachlorobiphenyl                    106                                 70424-69-0         CP1, 4CL, 2M
2,3,3',4',5-Pentachlorobiphenyl                   107                                 70424-68-9         CP1, 4CL, 2M
2,3,3',4,5'-Pentachlorobiphenyl                   108                                 70362-41-3         CP1, 4CL, 2M
2,3,3',4,6-Pentachlorobiphenyl                    109                                 74472-35-8         4CL, 2M
2,3,3',4',6-Pentachlorobiphenyl                   110                                38380-03-9         4CL, 2M
2,3,3',5,5'-Pentachlorobiphenyl                   111                                 39635-32-0         CP1, 4CL, 2M
2,3,3',5,6-Pentachlorobiphenyl                    112                                 74472-36-9         4CL, 2M
2,3,3',5',6-Pentachlorobiphenyl                   113                                 68194-10-5         4CL, 2M
2,3,4,4',5-Pentachlorobiphenyl                    114                                 74472-37-0         CP1, 4CL, PP, 2M
2,3,4,4',6-Pentachlorobiphenyl                    115                                 74472-38-1         4CL, PP
2,3,4,5,6-Pentachlorobiphenyl                     116                                 18259-05-7         4CL, 2M
2,3,4',5,6-Pentachlorobiphenyl                     117                                 68194-11-6         4CL, 2M
2,3',4,4',5-Pentachlorobiphenyl                    118                                 31508-00-6         CP1, 4CL, PP, 2M
2,3',4,4',6-Pentachlorobiphenyl                    119                                 56558-17-9         4CL, PP
2,3',4,5,5'-Pentachlorobiphenyl                    120                                 68194-12-7         CP1, 4CL, 2M
2,3',4,5',6-Pentachlorobiphenyl                    121                                 56558-18-0         4CL, 2M
2,3,3',4',5'-Pentachlorobiphenyl                   122                                 76842-07-4         CP1, 4CL, 2M
2,3',4,4',5'-Pentachlorobiphenyl                   123                                 65510-44-3         CP1, 4CL, PP, 2M
2,3',4',5,5'-Pentachlorobiphenyl                    124                                 70424-70-3         CP1, 4CL, 2M
2,3',4',5',6-Pentachlorobiphenyl                    125                                 74472-39-2         4CL, 2M
3,3',4,4',5-Pentachlorobiphenyl                     126                                 57465-28-8         CP0, 4CL, PP, 2M
3,3',4,5,5'-Pentachlorobiphenyl                     127                                 39635-33-1         CP0, 4CL, 2M
2,2',3,3',4,4'-Hexachlorobiphenyl                   128                                 38380-07-3         4CL, PP, 2M
2,2',3,3',4,5-Hexachlorobiphenyl                    129                                 55215-18-4         4CL, 2M
2,2',3,3',4,5'-Hexachlorobiphenyl                   130                                 52663-66-8         4CL, 2M
2,2',3,3',4,6-Hexachlorobiphenyl                    131                                 61798-70-7         4CL, 2M
2,2',3,3',4,6'-Hexachlorobiphenyl                   132                                 38380-05-1         4CL, 2M
2,2',3,3',5,5'-Hexachlorobiphenyl                   133                                 35694-04-3         4CL, 2M
2,2',3,3',5,6-Hexachlorobiphenyl                    134                                 52704-70-8         4CL, 2M
2,2',3,3',5,6'-Hexachlorobiphenyl                    135                                 52744-13-5         4CL, 2M
2,2',3,3',6,6'-Hexachlorobiphenyl                    136                                 38411-22-2         4CL, 2M
2,2',3,4,4',5-Hexachlorobiphenyl                     137                                 35694-06-5         4CL, PP, 2M
2,2',3,4,4',5'-Hexachlorobiphenyl                    138                                 35065-28-2         4CL, PP, 2M
2,2',3,4,4',6-Hexachlorobiphenyl                     139                                 56030-56-9         4CL, PP
2,2',3,4,4',6'-Hexachlorobiphenyl                    140                                 59291-64-4         4CL, PP
2,2',3,4,5,5'-Hexachlorobiphenyl                     141                                 52712-04-6         4CL, 2M
2,2',3,4,5,6-Hexachlorobiphenyl                      142                                 41411-61-4         4CL, 2M
2,2',3,4,5,6'-Hexachlorobiphenyl                     143                                 68194-15-0         4CL, 2M
2,2',3,4,5',6-Hexachlorobiphenyl                     144                                 68194-14-9         4CL, 2M
2,2',3,4,6,6'-Hexachlorobiphenyl                     145                                 74472-40-5         4CL
2,2',3,4',5,5'-Hexachlorobiphenyl                     146                                 51908-16-8         4CL, 2M
2,2',3,4',5,6-Hexachlorobiphenyl                      147                                 68194-13-8         4CL, 2M
2,2',3,4',5,6'-Hexachlorobiphenyl                     148                                 74472-41-6         4CL, 2M
2,2',3,4',5',6-Hexachlorobiphenyl                     149                                 38380-04-0         4CL, 2M
2,2',3,4',6,6'-Hexachlorobiphenyl                     150                                 68194-08-1         4CL
2,2',3,5,5',6-Hexachlorobiphenyl                      151                                 52663-63-5         4CL, 2M
2,2',3,5,6,6'-Hexachlorobiphenyl                      152                                 68194-09-2         4CL, 2M
2,2',4,4',5,5'-Hexachlorobiphenyl                      153                                 35065-27-1         4CL, PP, 2M
2,2',4,4',5,6'-Hexachlorobiphenyl                      154                                60145-22-4         4CL, PP
2,2',4,4',6,6'-Hexachlorobiphenyl                      155                                 33979-03-2         4CL, PP
2,3,3',4,4',5-Hexachlorobiphenyl                       156                                 38380-08-4         CP1, 4CL, PP, 2M
2,3,3',4,4',5'-Hexachlorobiphenyl                      157                                 69782-90-7         CP1, 4CL, PP, 2M
2,3,3',4,4',6-Hexachlorobiphenyl                       158                                 74472-42-7         4CL, PP, 2M
2,3,3',4,5,5'-Hexachlorobiphenyl                       159                                 39635-35-3         CP1, 4CL, 2M
2,3,3',4,5,6-Hexachlorobiphenyl                        160                                 41411-62-5         4CL, 2M
2,3,3',4,5',6-Hexachlorobiphenyl                       161                                 74472-43-8         4CL, 2M
2,3,3',4',5,5'-Hexachlorobiphenyl                       162                                 39635-34-2         CP1, 4CL, 2M
2,3,3',4',5,6-Hexachlorobiphenyl                        163                                 74472-44-9         4CL, 2M
2,3,3',4',5',6-Hexachlorobiphenyl                       164                                 74472-45-0         4CL, 2M
2,3,3',5,5',6-Hexachlorobiphenyl                        165                                 74472-46-1         4CL, 2M
2,3,4,4',5,6-Hexachlorobiphenyl                         166                                 41411-63-6         4CL, PP, 2M
2,3',4,4',5,5'-Hexachlorobiphenyl                        167                                 52663-72-6         CP1, 4CL, PP, 2M
2,3',4,4',5',6-Hexachlorobiphenyl                        168                                 59291-65-5         4CL, PP, 2M
3,3',4,4',5,5'-Hexachlorobiphenyl                        169                                 32774-16-6         CP0, 4CL, PP, 2M
2,2',3,3',4,4',5-Heptachlorobiphenyl                    170                                 35065-30-6         4CL, PP, 2M
2,2',3,3',4,4',6-Heptachlorobiphenyl                    171                                 52663-71-5         4CL, PP, 2M
2,2',3,3',4,5,5'-Heptachlorobiphenyl                    172                                 52663-74-8         4CL, 2M
2,2',3,3',4,5,6-Heptachlorobiphenyl                     173                                 68194-16-1         4CL, 2M
2,2',3,3',4,5,6'-Heptachlorobiphenyl                    174                                 38411-25-5         4CL, 2M
2,2',3,3',4,5',6-Heptachlorobiphenyl                    175                                 40186-70-7         4CL, 2M
2,2',3,3',4,6,6'-Heptachlorobiphenyl                    176                                 52663-65-7         4CL, 2M
2,2',3,3',4,5',6'-Heptachlorobiphenyl                   177                                 52663-70-4         4CL, 2M
2,2',3,3',5,5',6-Heptachlorobiphenyl                    178                                 52663-67-9         4CL, 2M
2,2',3,3',5,6,6'-Heptachlorobiphenyl                    179                                 52663-64-6         4CL, 2M
2,2',3,4,4',5,5'-Heptachlorobiphenyl                    180                                 35065-29-3         4CL, PP, 2M
2,2',3,4,4',5,6-Heptachlorobiphenyl                     181                                 74472-47-2         4CL, PP, 2M
2,2',3,4,4',5,6'-Heptachlorobiphenyl                    182                                 60145-23-5         4CL, PP, 2M
2,2',3,4,4',5',6-Heptachlorobiphenyl                    183                                 52663-69-1         4CL, PP, 2M
2,2',3,4,4',6,6'-Heptachlorobiphenyl                    184                                 74472-48-3         4CL, PP
2,2',3,4,5,5',6-Heptachlorobiphenyl                     185                                 52712-05-7         4CL, 2M
2,2',3,4,5,6,6'-Heptachlorobiphenyl                     186                                 74472-49-4         4CL, 2M
2,2',3,4',5,5',6-Heptachlorobiphenyl                    187                                 52663-68-0         4CL, 2M
2,2',3,4',5,6,6'-Heptachlorobiphenyl                    188                                 74487-85-7         4CL, 2M
2,3,3',4,4',5,5'-Heptachlorobiphenyl                    189                                 39635-31-9         CP1, 4CL, PP, 2M
2,3,3',4,4',5,6-Heptachlorobiphenyl                     190                                 41411-64-7         4CL, PP, 2M
2,3,3',4,4',5',6-Heptachlorobiphenyl                    191                                 74472-50-7         4CL, PP, 2M
2,3,3',4,5,5',6-Heptachlorobiphenyl                     192                                 74472-51-8         4CL, 2M
2,3,3',4',5,5',6-Heptachlorobiphenyl                    193                                 69782-91-8         4CL, 2M
2,2',3,3',4,4',5,5'-Octachlorobiphenyl                   194                                 35694-08-7         4CL, PP, 2M
2,2',3,3',4,4',5,6-Octachlorobiphenyl                    195                                 52663-78-2         4CL, PP, 2M
2,2',3,3',4,4',5,6'-Octachlorobiphenyl                    196                                 42740-50-1         4CL, PP, 2M
2,2',3,3',4,4',6,6'-Octachlorobiphenyl                    197                                 33091-17-7         4CL, PP, 2M
2,2',3,3',4,5,5',6-Octachlorobiphenyl                     198                                 68194-17-2         4CL, 2M
2,2',3,3',4,5,5',6'-Octachlorobiphenyl                    199                                 52663-75-9         4CL, 2M
2,2',3,3',4,5,6,6'-Octachlorobiphenyl                     200                                 52663-73-7         4CL, 2M
2,2',3,3',4,5',6,6'-Octachlorobiphenyl                     201                                 40186-71-8         4CL, 2M
2,2',3,3',5,5',6,6'-Octachlorobiphenyl                     202                                 2136-99-4         4CL, 2M
2,2',3,4,4',5,5',6-Octachlorobiphenyl                      203                                 52663-76-0         4CL, PP, 2M
2,2',3,4,4',5,6,6'-Octachlorobiphenyl                      204                                 74472-52-9         4CL, PP, 2M
2,3,3',4,4',5,5',6-Octachlorobiphenyl                       205                                 74472-53-0         4CL, PP, 2M
2,2',3,3',4,4',5,5',6-Nonachlorobiphenyl                  206                                 40186-72-9         4CL, PP, 2M
2,2',3,3',4,4',5,6,6'-Nonachlorobiphenyl                  207                                 52663-79-3         4CL, PP, 2M
2,2',3,3',4,5,5',6,6'-Nonachlorobiphenyl                  208                                 52663-77-1         4CL, 2M
Decachlorobiphenyl                                                 209                                 2051-24-3         4CL, PP, 2M
PCB congeners can be placed into three categories based on the degree
of chlorination on the
ortho positions of the molecule (these positions are closest
to the single bond joining the two aromatic rings; see figure)
:

1) non-ortho-chlorinated congeners
2) congeners chlorinated in only one
ortho position (mono-ortho PCBs)
3) congeners chlorinated in two or more
ortho positions

The non- and mono-ortho chlorinated congeners exhibit a co-planar structure similar to
that of dioxin (2,3,7,8-tetrachlorodibenzo-p-dioxin), and twelve of these have toxic
effects like dioxins:
77, 81, 105, 114, 118, 123, 126, 156, 157, 167, 169 and 189
(http://www.epa.gov/epawaste/hazard/tsd/pcbs/index.htm).  While the toxicity of the latter
PCBs has some understanding, there is almost no understanding of the sub-lethal
effects (e.g., endocrine and phenotypic disruption) of these and the many other PCBs.  

Work at EEL is directed at determining what effects the different PCB congeners may
have in California wildlife.